International Research journal of Management Science and Technology

  ISSN 2250 - 1959 (online) ISSN 2348 - 9367 (Print) New DOI : 10.32804/IRJMST

Impact Factor* - 6.2311


**Need Help in Content editing, Data Analysis.

Research Gateway

Adv For Editing Content

   No of Download : 308    Submit Your Rating     Cite This   Download        Certificate

KINETICS OF OXIDATION OF ALANINE BY N-CHLOROBENZAMIDE IN AQUEOUS ACETIC ACID MEDIUM

    2 Author(s):  T.LATHA, R.MANIKANDAN

Vol -  9, Issue- 8 ,         Page(s) : 31 - 35  (2018 ) DOI : https://doi.org/10.32804/IRJMST

Abstract

Kinetics of oxidation of Alanine acid by N-chlorobenzamide was studied in aqueous acetic acid medium at different concentrations of NCB, amino acid, H+, NaClO4 and at different solvent polarities at constant temperature. The study reveals the following kinetic features.The reaction follows first order kinetics with respect to Alanine and N-chlorobenzamide. The rate of the reaction is not affected by an increase in the concentration of sodium perchlroate. The rate of the reaction increase with increase in the acetic acid content in the solvent mixture acetic acid and water. An increase in the concentration of the H+ ion increases the rate of the reaction linearly.

1. F.A. Patrocinio and J. S Paulo Moran, J. Organomet .Chem., 603, 220, 2000.
2. (a) A. L. Harihar, M.R Kembhavi and S. T. Nadibewoor, J. Indian Chem. Soc., 76, 128, 1999 (b) Puttaswamy, T. M. Anuradha, R. Ramachandrappa, N. M. Made Gowda, Int. J. Chem. Kinetics, 32 (4), 221-230, 2000. (c) S. Ananda, M. B. Jagadeesha, Puttaswamy, B. M. Venkatesha, T.K. Vinod and N. M. Made Gowda, Int. J. Chem. Kinetics, 32(12), 776, 2000
3. (a) N .A. Mohamed Farook, R.Prabakaran, S. Rahini, R. Senthil Kumar,  G. Rajamahendran and B. Gopalakrishnan, E.J.Chem., 1(2), 127, 2004.  (b) B. ThimmeGowda, MaheshaShetty, J Phy Org Chem, 17 (10), 848  2004. (c) Ghanat K. Joshi, Y.R. Katre and Ajaya K. Singh, J Surfactants  and Detergents, 9 (3), 231, 2006
 4.     (a) P.G. Reddy, T. Kistayya, J. A. Khan and S. Kandlikar, Z. Phys. Chem (Leipzig), 269, 1253, 1988. (b) D. S. Mahadevappa, S. Ananda, A.S.A. Murthy and K. S. Rangappa, Reaction Kinetics  and  Catalysis Letters, 23 (1-2), 1983. 
5. (a) M. S. Ramachandran, D. Easwaramoorthy V. Rajasingh and T. S. Vivekanandam, Bull. Chem. Soc. Jpn., 63, 2397, 1990. (b). DidcyLaloo, K. Mahendra and Mahanti, J Phy Org Chem, 3 (12), 799 – 802, 2004. (c) S. Ananda, Ravi J. D. Saldanha, K. M. L. Rai, and B. M. Venkatesha, Int. J. Chem. Kinetics, 31 (10), 744, 1999
6. (a) P. S. Radhakrishnamurthi, B.M. Sasmal and D.P. Patnaik, Indian J. Chem., 25A, 69, 1986. (b) Puttaswamy and NirmalaVaz, Proc. Indian Acad. Sci., 113(4), 325-332, 2001 (c) D.S. Mahadevappa, K.S.Rangappa, N. M. M. Gowda and B. ThimmeGowda, Int. J. Chem. Kinetics, 14 (11), 1183-1197, 2004. 
7.     (a) K. Vivekanandan and K. Nambi, J. Indian Chem. Soc., 76, 198, 1999.  (b) V. SurenderRao, B. Sethuram and T. NavaneethRao, Int. J. ChemKinetics, 11(2), 165, 2004. (c) Puttaswamy, NirmalaVaz, N.M. Made Gowda, Int. J. Chem. Kinetics, 33 (8), 480, 2001
8.    (a)M.S. Ramachandran, R. Santhanalakshmi and D. Eswaramoorthy, Oxid. Comm., 21, 230, 1998. (b) M.C Mary, J. D. D’souza and B. Gowda, Oxid. Commun., 25 (2), 294-304, 2002. 

*Contents are provided by Authors of articles. Please contact us if you having any query.






Bank Details