SYNTHESIS OF COPPER AND NICKEL BASED SURFACTANTS AND THEIR CHAREACTERIZATION USING SPECTROSCOPIC, THERMODYNAMIC AND CONDCTOMETRIC METHODS
1
Author(s):
AMAN MALHOTRA
Vol - 4, Issue- 2 ,
Page(s) : 541 - 553
(2013 )
DOI : https://doi.org/10.32804/IRJMST
Abstract
Metal(Copper and Nickel) surfactants from metal acetate and dodecylamineacetate has been synthesized The entities formed has been characterized through various spectroscopic techniques (viz. FTIR, NMR and UV) and elemental analysis. To understand the supramolecular assembly, cmc and thermodynamics of micellization has been determined over a range of temperature using conductivity measurements. The size of the micellar aggregates has been determined using DLS.
- Martinez, A.G.; Vida, Y.; Gutierrez, D.D.; Albuquerque, R.Q.; Cola, L.D. Inorg. Chem. 2008, 47, 9131.
- Liang, X.; Campopiano, D.J.; Sadler, P.J. Chem. Soc. Rev. 2007, 36, 968.
- Jervis, H.B.; Raimondi, M.E.; Raja, R.; Maschmeyer, T.; Seddon, J.M.; Bruce, D.W. Chem. Comm. 1999, 2031.
- Danks, M.J.; Jervis, H.B.; Notwotny, M.; Zhou, W.; Maschmeyer, T.A.; Bruce, D.W. Catal. Letters 2002, 82, 95.
- Chu, B.W.-K.; Yam, V.W.-W. Inorg. Chem. 2001, 40, 3324.
- Kimura, E.; Hashimoto, H.; Koike, T. J. Am. Chem. Soc. 1996, 118, 10963.
- Hay, R.W.; Govan, N.; Parchment, K.E. Inorg. Chem. Comm. 1998, 1, 228.
- Weijnen, J.G.J.; Koudijs, A.; Engbersen, J.F.J.J. Chem. Soc., Perkin Trans. 2 1991, 1121.
- Manabe, K.; Mori, Y.; Wakabayashi, T.; Nagayama, S.; Kobayashi, S. J. Am. Chem. Soc. 2000, 122, 7202.
- Goedheijt, M.S.; Hanson, B.E.; Reek, J.N.H.; Kamer, P.C.J.; van Leeuwen, P.W.N.M. J. Am. Chem. Soc. 2000, 122, 1650.
- Tascioglu, S. Tetrahedron 1996, 52, 11113.
- Vriezema, D.M.; Aragones, M.C.; Elemans, J.A.A.W.; Cornelissen, J.J.L.M.; Rowan, A.E.; Nolte, R.J.M. Chem. Rev. 2005, 105, 1445.
- Griffiths, P.C.; Fallis, I.A.; Chuenpratoom, T.; Watanesk, R. Adv. Colloid Interface Sci. 2006, 122, 107.
- Gutierrez, D.D.; Paoli, G.D.; Martinez, A.G.; Ginocchietti, G.; Ebeling, D.; Eiser, E.; Cola, L.D.; Elsevier, C.J. J. Mater. Chem. 2008, 18, 2762.
- Schmid, G.; Corain, B. Eur. J. Inorg. Chem. 2003, 2003, 3081.
- Erb, U.; Aust, K.T.; Palumbo G. Nanostructured Materials. Processing, Properties and Potential Applications Noyes, New York, 2002, 179.
- Goddard III, W.A.; Brenner, D.W.; Lyshevski, S.E.; Iafrate, G.J. Handbook of Nanoscience, Engineering and Technology CRC, Boca Raton, 2002.
- Mulvaney, P. Nanoscale Materials in Chemistry Wiley, New York, 2001, 121.
- Tang, Z.; Ozturk, B.; Wang, Y.; Kotov, N.A. J. Phys. Chem. B 2004, 108, 6927.
- McBain, S.C.; Yiu, H.H.P.; Dobson, J. Int. J. Nanomedicine 2008, 3, 169.
- Brust, M.; Walker, M.; Bethell, D.; Schiffrin, D.J.; Whyman, R. J. Chem. Soc., Chem. Comms. 1994, 801.
|