International Research journal of Management Science and Technology

  ISSN 2250 - 1959 (online) ISSN 2348 - 9367 (Print) New DOI : 10.32804/IRJMST

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OXIDATIVE TRANSFORMATION OF GLYCOLIC ACID BY PYRIDINIUM DICHROMATE IN NON –AQUEOUS MEDIUM KINETIC AND MECHANISTIC STUDY

    2 Author(s):  RAKESH KUMAR SHARMA ,B.K. DANGARH

Vol -  12, Issue- 1 ,         Page(s) : 108 - 111  (2021 ) DOI : https://doi.org/10.32804/IRJMST

Abstract

The Alpha Hydroxy acids (AHA) are naturally occurring organic acids . The oxidation of Glycolic acid pyridiniumdicromate has been studied spectrophotometrically in the presence of para-toluensulphonic acid (PTSA) in dimathyl sulphoxide (DMSO) as a solvent. Pyridinium dichromate (C5H5NH)2 Cr2O7 is an orange colored solid used as an oxidizing agent. PDC is less acidic than pcc (Pyridiniumchloro chromate) and hence is more suitable in the oxidation of acid sensitivity compounds.

Mehrotra R.N. ; Eur . Chem.Bull , (2013) , 2 (10) , 758
Banerji J. , Banerji K.K. , Kotai L. , Sharma D. , Sharma P.K.; J. Ind. Chem.. soc. (2011) , 88(12) , 1879 

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